Module A1.3 - Physical Chemistry

Coordinator: apl. Prof. Dr. Michael Schmitt

Lecturers: Dr. Dana Cialla-May, Prof. Dr. Ute Neugebauer, Dr. Jer-Shing Huang, Prof. Dr. Jürgen Popp, apl. Prof. Dr. Michael Schmitt

Schedule:

Lectures and Exercises:
Monday 12.15 - 13.45 (SR 121) +
Thursday 08.15 - 09.45 (SR 116, August-Bebel-Str. 4) +
Friday 08.15 - 09.45 (SR 116, August-Bebel-Str. 4)

Contents:

Week	Lecturer	Subject	Download
Week 1 16.10.2017	Neugebauer	Introduction and overview history of thermodynamics definitions
19.10.2017	Neugebauer	First law of thermodynamics work and heat path dependence of work internal energy
20.10.2017	Neugebauer	Thermochemistry standard enthalpy changes Hess’ law spontaneous reactions
Week 2 23.10.2017	Cialla-May	Seminar
26.10.2017	Neugebauer	Second law of thermodynamics dispersal of energy entropy Helmholtz and Gibbs energies
27.10.2017	Neugebauer	Physical transformations Phase diagrams chemical potential
Week 3 30.10.2017	Cialla-May	Seminar
02.11.2017	Neugebauer	Phase transistions equilibria in one- and two component systems
03.11.2017	Neugebauer	Transport phenomena osmosis dialysis diffusion Fick's law
Week 4 06.11.2017	Cialla-May	Seminar
09.11.2017	Neugebauer	Mixtures boiling diagrams thermodynamics of mixing activities
10.11.2017	Neugebauer	Chemical equilibrium I equilibrium constant LeChatelier's principle Henderson-Hasselbalch equation
Week 5 13.11.2017	Neugebauer	Chemical equilibrium II titration curves application of equilibrium calculations to drug design
16.11.2017	Cialla-May	Seminar
17.11.2017	Cialla-May	Seminar
Week 6 20.11.2017	Neugebauer	Introduction to equilibrium electrochemistry I electrochemical reactions cell potential
23.11.2017	Neugebauer	Introduction to equilibrium electrochemistry II Nernst equation standard potential
24.11.2017	Cialla-May	Seminar
Week 7 27.11.2017	Huang / Schmitt	Chemical kinetics empirical methods rates of reaction reaction order molecularity first order reactions
30.11.2017	Huang / Schmitt	Rate laws of chemical reactions I
01.12.2017	Cialla-May	Seminar
Week 8 04.12.2017	Huang / Schmitt	Rate laws of chemical reactions II
07.12.2017	Huang / Schmitt	Theory of speed reactions
08.12.2017	Cialla-May	Seminar
Week 9 11.12.2017	Huang /Schmitt	Kinetics of complex reactions
14.12.2017	Huang / Schmitt	Enzyme kinetics
15.12.2017	Cialla-May	Seminar
Week 10 11.12.2017	Huang / Schmitt	Experimental methods to measure kinetics
21.12.2017	Huang / Schmitt	Breakdown of classical mechanics black body radiation photoelectric effect Compton effect
22.12.2017	Cialla-May	Seminar
Week 11 08.01.2018	Huang / Schmitt	Waves and photons wave-particle duality Heisenberg uncertainty prionciple de Broglie relationship
11.01.2018	Huang / Schmitt	Basic principles of quantum mechanics Schrödinger equation wavefunction (Born interpretation) operator quantization
12.01.2018	Cialla-May	Seminar
Week 12 15.01.2018	Huang / Schmitt	Methods & applications of quantum mechanics particle in a box harmonic oscillator
18.01.2018	Huang / Schmitt	Atomic structure & spectra I hydrogen atom atomic spectra of hydrogen like atoms
19.01.2018	Cialla-May	Seminar
Week 13 22.01.2018	Huang / Schmitt	Atomic structure & spectra II structure and spectra of multielectron atoms Pauli principle Hund’s rule
25.01.2018	Huang / Schmitt	Molecular structure I Born-Oppenheimer approximation valence bond theory (hybridization)
26.01.2018	Cialla-May	Seminar
Week 14 29.01.2018	Huang / Schmitt	Molecular structure II variational principle perturbation theory
01.02.2018	Huang / Schmitt	Molecular structure III molecular orbital theory linear combination of atomic orbitals Slater determinat Hückel approximation
02.02.2018	Cialla-May	Seminar
Week 15 05.02.2018	Huang / Schmitt	Hartree-Fock method electron correlation configuration interaction
08.02.2018	Huang / Schmitt	Density functional theory Hohenberg-Kohn theorem Kohn-Sham approach
09.02.2018	Cialla-May	Seminar