Module A1.3 - Physical Chemistry
Coordinator
apl. Prof. Dr. Michael Schmitt
Lecturers
Dr. Dana Cialla-May, Prof. Dr. Ute Neugebauer, Dr. Jer-Shing Huang, apl. Prof. Dr. Michael Schmitt
Schedule
- Lectures + Exercises:
Monday 12.30 - 14.00 (HS Bachstr. 18k) +
Thursday 08.15 - 09.45 (HS Bachstr. 18k)
Friday 08.15 - 09.45 (SR 103, August-Bebel-Str. 4) - Exam:
Date: 09.03.2022
Time: 10:00-12:00
Location: Döbereiner Hörsaal (Am Steiger 3, 07743 Jena)
Registration
Please enrol in Friedolin for this course. For the exam registration via DOSIS within the first 10 weeks after the start of the lecture period is necessary. You will get a note via e-mail when the DOSIS portal is open.
Contents:
| Week | Lecturer | Subject |
|
Week 1 18.10.2021 |
Schmitt |
Introduction and Overview history thermodynamics, definitions |
| 21.10.2021 | Schmitt |
First law of thermodynamics work and heat, path dependence of work, Internal energy |
| 22.10.2021 | Cialla-May | seminar |
|
Week 2 25.10.2021 |
Schmitt |
Thermochemistry standard enthalpy changes, Hess’s law, spontaneous reactions |
| 28.10.2021 | Schmitt |
Second law of thermodynamics dispersal of energy, entropy, Helmholtz and Gibbs energies |
| 29.10.2021 | Schmitt |
Physical transformation Phase diagrams, Chemical potential |
|
Week 3 01.11.2021 |
Cialla-May | seminar |
|
04.11.2021 |
Schmitt |
Transport phenomena osmosis, dialysis, diffusion, Fick's law |
|
05.11.2021 |
Cialla-May | seminar |
|
Week 4 08.11.2021 |
Huang |
Chemical equilibrium I equilibrium constant, LeChatelier’s principle, Henderson-Hasselbalch equation |
|
11.11.2021 |
Huang |
Introduction to equilibrium electrochemistry I electrochemical reactions, cell potential |
|
12.11.2021 |
Cialla-May | seminar |
|
Week 5 15.11.2021 |
Huang |
Introduction to equilibrium electrochemistry II Nernst equation, standard potential |
| 18.11.2021 | Huang | Chemical kinetics: empirical methods, rates of reactions |
| 19.11.2021 | Cialla-May | seminar |
|
Week 6 22.11.2021 |
Huang | Rate laws of chemical reactions I |
|
25.11.2021 |
Huang | Kinetics of complex reactions |
|
26.11.2021 |
Cialla-May | seminar |
|
Week 7 29.11.2021 |
Huang | Rate laws of chemical reactions II |
|
02.12.2021 |
Huang | Speed of reactions I |
|
03.12.2021 |
Cialla-May | seminar |
|
Week 8 06.12.2021 |
Huang | Speed of reactions II |
|
09.12.2021 |
Huang | Experimental methods to measure kinetics |
|
10.12.2021 |
Cialla-May | seminar |
|
Week 9 13.12.2021 |
Huang |
Breakdown of classical mechanics black body radiation, photoelectric effect, Compton effect etc. |
|
16.12.2021 |
Huang | Wave-particle duality, de Broglie relationship, wavefunction, operator |
| 17.12.2021 | Cialla-May | seminar |
|
Week 10 03.01.2022 |
Neugebauer | Heisenberg Uncertainty principle, Schrödinger equation, quantization |
|
06.01.2022 |
Neugebauer | Particle in a box; harmonic oscillator |
| 07.01.2022 | Cialla-May | seminar |
|
Week 11 10.01.2022 |
Neugebauer | Rotation: particle on a circle |
|
13.01.2022 |
Neugebauer | Hydrogen atom; atomic spectra of hydrogen like atoms |
| 14.01.2022 | Cialla-May | seminar |
|
Week 12 17.01.2022 |
Neugebauer |
Structure and spectra of multielectron atoms Pauli principle, Hund’s rule |
|
20.01.2022 |
Neugebauer | Molecular structure: Born-Oppenheimer approximation, valence bond theory (hybridization) |
| 21.01.2022 | Cialla-May | seminar |
|
Week 13 24.01.2022 |
Neugebauer | Molecular structure: Variational principle; perturbation theory |
|
27.01.2022 |
Neugebauer |
Molecular structure: Molecular orbital theory linear combination of atomic orbitals |
| 28.01.2022 | Cialla-May | seminar |
|
Week 14 31.01.2022 |
Neugebauer |
Molecular structure: Molecular orbital theory Slater determinat, Hückel approximation |
|
03.02.2022 |
Neugebauer |
Hartree-Fock method electron correlation |
| 04.02.2022 | Cialla-May | seminar |
|
Week 15 07.02.2022 |
Neugebauer |
Hartree-Fock method configuration interaction |
|
10.02.2022 |
Neugebauer |
Density functional theory Hohenberg-Kohn Theorem, Kohn-Sham approach |
| 11.02.2022 | Cialla-May | seminar |